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When experts talk about the energy systems of the future, they often come back to one specific number: 0.1 milligrams per square centimeter (0.1 mg/cm²). This seemingly insignificant number could be critical to moving green hydrogen from a promising concept to an economic reality.
Thomas Barregren • January 15, 2025
Green hydroÂgen is a promisÂing soluÂtion for decarÂbonizÂing indusÂtriÂal processÂes, but high proÂducÂtion costs are holdÂing back develÂopÂment. A key botÂtleÂneck is the reliance on the preÂcious metÂal iridÂiÂum in the elecÂtrolÂyÂsis. To make the techÂnolÂoÂgy ecoÂnomÂiÂcalÂly viable, iridÂiÂum use must be reduced to 0.1 milÂligrams per square cenÂtimeÂter – a techÂniÂcal chalÂlenge that could deterÂmine the future of hydroÂgen as an enerÂgy carrier.
HydroÂgen is not only the simÂplest and most abunÂdant eleÂment in the uniÂverse, it is also a funÂdaÂmenÂtal part of our indusÂtriÂal econÂoÂmy. GlobÂal demand is approxÂiÂmateÂly 95 milÂlion tons per year, with indusÂtriÂal processÂes accountÂing for more than 99 % of consumption.
In the petroÂchemÂiÂcal indusÂtry, hydroÂgen is essenÂtial for desulÂfuÂrÂizaÂtion and hydroÂcÂrackÂing in oil refinÂing. The chemÂiÂcal indusÂtry relies on hydroÂgen to proÂduce ammoÂnia for ferÂtilÂizÂer – a process that litÂerÂalÂly feeds half the world’s popÂuÂlaÂtion. Methanol proÂducÂtion, anothÂer major hydroÂgen conÂsumer, proÂvides indusÂtry with chemÂiÂcal buildÂing blocks for countÂless everyÂday products.
Less than 1 % of all hydroÂgen is proÂduced by elecÂtrolÂyÂsis using elecÂtricÂiÂty from renewÂable sources or nuclear powÂer. This low figÂure is due to the fact that hydroÂgen proÂduced in this way is 2–5 times more expenÂsive than hydroÂgen proÂduced from fosÂsil fuels. As a result, 96 % of all hydroÂgen is proÂduced directÂly or indiÂrectÂly from natÂurÂal gas, oil and coal, at low ecoÂnomÂic cost and a sky-high price for the cliÂmate. For every kiloÂgram of hydroÂgen proÂduced today, up to ten kiloÂgrams of carÂbon dioxÂide are released directÂly into the atmosphere.
UnforÂtuÂnateÂly, the cliÂmate cost pales in comÂparÂiÂson to the proÂducÂtion price. If the indusÂtry is to switch to green hydroÂgen – hydroÂgen proÂduced by elecÂtrolÂyÂsis of water using elecÂtricÂiÂty from renewÂable sources – the cost must come down to the same low price as its dirtÂiÂer cousins: gray, brown and black hydrogen.
HydroÂgen is one of the key means to achieve Net Zero EmisÂsions (NZE). In addiÂtion to being a raw mateÂrÂiÂal for indusÂtry, as it is today, hydroÂgen will perÂform two funcÂtions that are essenÂtial for reducÂing CO2 emissions:
In this way, hydroÂgen can conÂtribute 10 % of the emisÂsions reducÂtions needÂed to meet the tarÂget of no more than a 1.5 °C increase in globÂal warmÂing. But this will require much more hydroÂgen than today – and it will have to be low-emisÂsion hydroÂgen – hydroÂgen proÂduced by elecÂtrolÂyÂsis with green elecÂtricÂiÂty, from bioÂmass, or from fosÂsil fuels where carÂbon dioxÂide is capÂtured and stored.
In an NZE sceÂnario for 2050, the InterÂnaÂtionÂal EnerÂgy Agency (IEA) has calÂcuÂlatÂed that today’s hydroÂgen proÂducÂtion will have to douÂble by 2030 and increase sixÂfold by 2050, with 98 % being low-emisÂsion hydroÂgen. The IEA expects that 76 % of all hydroÂgen, or 327 out of 430 megaÂtons, will be proÂduced by electrolyzers.
There is litÂtle doubt that the marÂket for elecÂtrolyzÂers could explode in the comÂing years.
But…
This assumes that hydroÂgen proÂduced in an elecÂtrolyzÂer becomes comÂpetÂiÂtive with hydroÂgen proÂduced from fosÂsil fuels. The price of green hydroÂgen must thereÂfore be reduced by 50 to 80 %.
So what makes hydroÂgen made from cheap water and elecÂtricÂiÂty more expenÂsive than hydroÂgen made from expenÂsive natÂurÂal gas, oil and coal?
The root cause is the cost of buildÂing a PEM elecÂtrolyzÂer. More preÂciseÂly, one cruÂcial mateÂrÂiÂal driÂves this cost: iridium.
This preÂcious metÂal is essenÂtial for splitÂting water (H2O) into hydroÂgen (H2) and oxyÂgen (O2). It is used on the oxyÂgen-proÂducÂing side of the memÂbrane that sepÂaÂrates the oxyÂgen and hydroÂgen proÂducÂtion sides.
IridÂiÂum is one of the rarest eleÂments in the earth’s crust. 90 % comes from South Africa and ZimÂbabÂwe, with the remainÂing proÂducÂtion comÂing from RusÂsia and North AmerÂiÂca. It is so rare that it is not ecoÂnomÂiÂcalÂly viable to mine iridÂiÂum specifÂiÂcalÂly. Instead, it is extractÂed as a by-prodÂuct of platÂinum and nickÂel mining.
The globÂal supÂply of iridÂiÂum is and will remain very limÂitÂed – only 7–8 tons are proÂduced annuÂalÂly.1 This makes it one of the most expenÂsive metÂals in the world, 2–3 times more expenÂsive than gold.
It doesn’t take much iridÂiÂum per square cenÂtimeÂter of memÂbrane to powÂer the process – just 2 milÂligrams. Yet the metÂal accounts for 20–25 % of the cost of the plant. And the profÂit from large-scale operÂaÂtion is negÂliÂgiÂble because the memÂbrane surÂface area increasÂes in proÂporÂtion to the numÂber of megawatts the plant must handle.
IridÂiÂum is a must. IridÂiÂum is expenÂsive. And the price is not going down – in fact, it is going up as demand increasÂes. So what is the solution?
Use less iridium!
Tiny 2 milÂligrams may not sound like much. But it’s a huge amount comÂpared to what’s needÂed to powÂer the process. In theÂoÂry, an atom-thin layÂer of iridÂiÂum is enough to make hydroÂgen. But much more is used. This is due to mateÂriÂals engiÂneerÂing challenges.
But if green hydroÂgen is to be comÂpetÂiÂtive with dirty hydroÂgen, the amount of iridÂiÂum used must be sigÂnifÂiÂcantÂly reduced. There are already elecÂtrolyzÂers that use half the amount, and in the lab they have manÂaged to halve it again. But that is not enough.
To be comÂpetÂiÂtive, the amount of iridÂiÂum must be reduced by 95 perÂcent – to 0.1 milÂligrams per square cenÂtimeÂter. This is the holy grail of the hydroÂgen industry.
When you break down the numÂbers, it becomes clear why 0.1 mg/​cm² is the holy grail.
At today’s depoÂsiÂtion rates of 1–2 mg/​cm², one gigawatt of elecÂtrolyzÂer capacÂiÂty requires about 400 kg of iridÂiÂum – a stagÂgerÂing 5 % of the world’s annuÂal proÂducÂtion. At an iridÂiÂum price of about 150,000 USD per kiloÂgram,2 the catÂaÂlyst cost alone for such a plant is 60 milÂlion USD. A reducÂtion to 0.1 mg/​cm² would reduce this cost to 6 milÂlion USD – a draÂmatÂic difÂferÂence that funÂdaÂmenÂtalÂly changes the calÂcuÂlus for large-scale hydroÂgen projects.
From a supÂply chain perÂspecÂtive, 0.1 mg/​cm² is even more critÂiÂcal. With today’s techÂnolÂoÂgy at 1–2 mg/​cm², the use of elecÂtrolyzÂers would quickÂly conÂsume more iridÂiÂum than is availÂable, and prices would skyÂrockÂet. At 0.1 mg/​cm², the equaÂtion is very difÂferÂent. Less than 30 kg of iridÂiÂum would be required to build one gigawatt of elecÂtrolyzÂer capacÂiÂty. AnnuÂal iridÂiÂum proÂducÂtion, along with recyÂcling of spent catÂaÂlysts, would be more than enough to meet the 2050 tarÂgets – while meetÂing the needs of othÂer critÂiÂcal industries.
For over twenÂty years, we have develÂoped a unique capaÂbilÂiÂty to preÂciseÂly grow elecÂtriÂcalÂly conÂnectÂed carÂbon nanofibers. Our busiÂness idea is to use this capaÂbilÂiÂty to solve comÂplex mateÂriÂals engiÂneerÂing chalÂlenges in wholÂly owned subÂsidiaries. When we recÂogÂnized the hydroÂgen industry’s chalÂlenge to reduce iridÂiÂum usage to 0.1 mg/​cm², it was natÂurÂal to creÂate Smoltek HydroÂgen to find the Holy Grail. Now we are very close.
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